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Gemstones
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Coloured Gemstones |
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| Gemstones
In South Africa |
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| Coloured
Gemstones
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Emplacement of gemstones in South Africa |
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Rocks consist of different
minerals, each with a definite chemical composition
and atomic structure. Rocks can be divided into three
main groups: |
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| 1.
Sedimentary Rock |
Sedimentary rocks:
Weathering, transportation, deposition of sediments.
Of importance in terms of gemstones is alluvial gravels
for diamond, agate and garnet deposits; |
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| 2.
Metamorphic rocks |
| Metamorphic rocks: pre-existing rocks that
have been altered by heat, pressure, stress and chemical
fluids; and |
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| 3.
Igneous rocks |
| Igneous rocks: originated from a molten
mass of magma that cooled and crystallised. |
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In South Africa, the
main “gem-containing” group is the igneous
rocks. Granite is a slow- cooled igneous rock consisting
of the minerals quartz, feldspar and mica. The last
phase of cooling and crystallisation in a water-rich
environment is known as a pegmatite. This rock is very
coarse grained and concentrates rare and incompatible
elements such as beryllium, boron, lithium, etc. Pegmatite
bodies often host gemstones such as beryl, emerald,
topaz and tourmaline. Unfortunately gemstones are not
evenly distributed within the pegmatite body but occur
in cavities (“pockets”) or in certain zones.
This makes the exploration and evaluation of gem-bearing
pegmatite deposits very difficult.
Important pegmatites that contain gemstones
are located in the Northern Cape (extended belt of 450
km in length and 50 km wide in the Steinkopf-Vioolsdrif,
Kakamas-Kenhardt areas); Mpumalanga (associated with
Archaean Greenstone belts, Gravelotte-Mica area); Northern
Province (Palakop, Pietersburg and Piet Retief areas).
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Beryl (Be3Al2Si6O18) |
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Geological occurrences:
Pegmatites associated with acid magmatic rocks and metamorphic
schists (metamorphic rock that can split into thin flakes).
Beryl has a hardness of 7,5-8 on the Mohs scale of hardness
(talc=1 and diamond=10), but is brittle. The colour
is translucent and white, but the presence of elements
in the crystal structure gives rise to different colours
and therefore to the different varieties. The different
gem varieties are: emerald (green), aquamarine (blue-green),
morganite (pink), heliodor (yellow), goshenite (colourless)
and bixbite (red). Beryl occurs in pegmatites of the
Northern Cape with colours varying from yellow-green,
through greenish white, to pink for beryl in lithium-rich
pegmatites. |
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Emerald (Be3Al2Si6O18): |
This dark-green variety
is the most valued of all the beryl varieties. It is
usually included and cracked, but the appearance can
be enhanced by oiling the stones and, in some cases,
filling the fractures with a filler (usually glass).
Because of its brittleness it is almost always fashioned
with octagonal step-cuts to reduce the risk of chipped
corners. The step cut also lightens the dark body colour
of the emeralds for a better appearance. Emerald occurs
where pegmatites “invade” ultramafic rocks
(schists). At this contact,
emerald crystallises as the result of metasomatism during
regional (low grade) metamorphism.
Emeralds are also synthesised by hydrothermal and flux-grown
processes, and these synthetics can be distinguished
from natural emerald by unnatural inclusions. Green
glass and composite stones are still used today to imitate
emerald. Emeralds are mined at the Cobra Emerald Mine
near Gravelotte by both excavation and underground operations.
Although top-quality flawless and vivid green stones
had been recovered, most
of the material is small, varies in colour and is cracked.
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Aquamarine (Be3Al2Si6O18): |
Gem-quality aquamarine
is transparent, flawless, and has a colour resembling
that of sea water (blue-green). Pale-blue and green
stones also occur. Heat treatment of green stones can
result in a darker blue colour. Glass and synthetic
spinel are generally used to imitate aquamarine, but
synthetic aquamarine has been manufactured for experimental
purposes.
Aquamarine occurs in Namaqualand (near Jakkalswater)
and the Murchison Range, east of Leydsdorp. |
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Morganite (Be3Al2Si6O18): |
This variety of beryl
has a rose-pink colour, although peach-coloured and
orange stones also exist. Gemquality morganite is found
in the Namaqualand pegmatites and in the vicinity of
Leydsdorp, Northern Province. Heliodor: It is also known
as yellow or golden beryl and is found in the Soutpansberg
district, between Messina and Pietersburg in the Northern
Province. |
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Goshenite and bixbite (Be3Al2Si6O18): |
| These varieties of beryl (colourless and
red, respectively) have not yet been discovered in South
Africa. |
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Copper Minerals |
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Azurite Cu2(OH)2(CO3)2
and Malachite Cu2(OH)2CO3 Azurite and malachite are
commonly associated with the weathered zone of copper
deposits, although these seldom occur in sufficient
quality or quantity to be exploited as a gemstone in
South Africa. Azurite is a dark-blue copper carbonate,
semitranslucent to opaque. It is too soft and usually
too dark to be faceted and is sometimes replaced by
malachite.
Malachite occurs mostly as layers of alternating lightgreen
and dark-green bands in massive or botryoidal bodies.
It seldom occurs as crystals. The material is too soft
to facet, but is cut as cabochons and beads for jewellery,
or used for carvings. It has been reported from the
mines at Messina and at Stavoren (Potgietersrus district),
Okiep, Postmasburg and in the vicinity of Pilgrim’s
Rest. |
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Corundum Al2O3 |
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Sapphire and Ruby
Geological occurrence: In pegmatites, schists, marbles,
gneisses (metamorphic, coarse- grained rock with alternating
layers formed by metamorphism) and alluvial gravel deposits.
Pure corundum is colourless, but usually traces of other
elements colour the material. The presence of chromium
oxides gives it a red colour resulting in the formation
of ruby. The term sapphire is used to describe all varieties
of corundum other than the red. The blue colour is due
to Fe+2 and Ti+4 ions in the lattice. Gem-quality stones
are always faceted. Translucent to opaque corundum is
usually cut as cabochons, and poorer-quality material
is used as abrasives. The appearance of rubies and sapphires
is sometimes enhanced by artificial processes such as
heat treatment. Many of the stones seen in the trade
are actually synthetic corundum, manufactured by the
Verneuil process which produces inclusions that show
the synthetic nature of these stones. Rubies are also
imitated by red glass, synthetic spinel, garnet and
composite stones with natural and/or synthetic parts.
Sapphires are usually imitated by cobalt-coloured glass
and synthetic spinel. Corundum is found over a wide
area including the Mpumalanga Province, with potential
deposits near Badplaas (dark, translucent sapphires),
Namaqualand (pink, yellow and crimson varieties in the
Kenhardt district) and south of Augrabies (poor-quality
sapphires and corundum). At Malalane, corundum occurs
in gneiss (metamorphic rock) where the host rock is
green mica (fuchsite). Although no transparent (gem
quality) corundum is found at these localities, they
are still important as collectors specimens. |
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Feldspar Group |
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Geological occurrences:
Among the most important rock- forming minerals, in
all granites and most igneous rocks and gneisses. A
few varieties of feldspar are considered to be gemstones.
A number of closely related minerals belong to this
group. |
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| South African varieties include:
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Moonstone (Plagioclase - (Na,Ca)AlSi3O8): |
Consists of alternate
layers of the two feldspar minerals, orthoclase and
albite. The interference of light by these thin layers
produces the sheen, or schiller, for which moonstone
is prized. The thickness of these layers determines
the colour, which may be white, bluishviolet or blue.
The lastmentioned colour is highly prized. Moonstone
also displays chatoyancy and is cut as cabochons. Moonstone
is found at the Eagle’s Nest Mine (Barberton district),
Mpumalanga Province. |
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Amazonite (K-feldspar /microcline - (K,Na)AlSi3O8): |
The colour of this
variety is green to blue-green, it being translucent
to opaque. Like all feldspars, amazonite has two directions
of good cleavage. Fashioned stones may break along these
directions if not handled with care. Amazonite occurs
as wellformed crystals to massive material. Gem material
is used for beads and cabochons, but not for carvings
because of the prominent cleavage. Northern Province:
Dark blue-green amazonite is found on the farm Honeydew
86 MR, Pietersburg district and in the vicinity of Leydsdorp.
Northern Cape Province: Localities include those at
Pofadder, Kenhardt district, Gordonia district, between
Steinkopf and Vioolsdrif and at Augrabies Falls National
Park. Unakite: Composed of pink feldspar and green epidote.
Cut as cabochons. Occurrences at Upington and Neilersdrif,
Northern Cape. |
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Garnet |
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Garnet General
formula:
L3M2(SiO4)3
L = Mg, Fe, Ca, Mn
M = Al, Fe, Cr
Geological occurrences: Garnets are found in metamorphic
and igneous rocks, and as rolled pebbles in alluvial
deposits. Gem-quality garnets are
transparent to translucent. Transparent material is
faceted, whereas semitranslucent and translucent material
is cut as cabochons. Garnet is one of the few gemstones
that does not react to known treatments. Synthetic garnets
have not been produced commercially, but are in some
cases simulated by glass and even synthetic corundum.
Variations in the composition of garnets produce a range
of species. |
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Almandine (Fe3Al2(SiO4)3 ) |
It is found in schists
and gneisses. Although brownish-red almandine garnet
is known in South Africa, there are no known deposits
of gem quality material. Pyrope (Mg3Al2(SiO4)3 ) is
often associated with diamonds in kimberlites. The alluvial
deposits are generally very small. Gem-quality pyrope
pebbles are found in the gravels of Orange and Vaal
Rivers. These water-worn stones with their frosted surfaces
exhibit a brownish-orange to red brown colour. A misleading
name given for these garnets is “Cape ruby”.
A purplishpink variety is known as rhodolite or Malaya
and is a “mixture” of almandine and pyrope
garnet. |
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Spessartine ( Mn3Al2(SiO4)3 ) |
This is the yellowish-orange
to brownishyellow variety known as hessonite or “cinnamon
stone”. Gem-quality transparent material is rare.
Orange, yellow and brown spessartine is found in the
Pegmatite Valley, Northern Cape Province. |
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Hydrogrossular (Ca3Al2(SiO4)3 ) |
Green and pink hydrogrossular
is also known as South African jade or Transvaal jade,
because of its jade-like appearance. It has the same
chemical composition as grossular garnet, but contains
water in the crystal structure. It is massive, translucent
to subtranslucent and has a waxy lustre. The colour
can be green, due to chromium, or pink, due to manganese.
Black, opaque inclusions of magnetite or chromite are
present. Massive hydrogrossular also forms a solid solution
with the mineral idocrase.
In the finest specimens the material is almost transparent
with an intense green colour and the black inclusions
are absent. It is cut as cabochons, carvings or jewellery
pieces. Hydroglossular is associated with the chromite
deposits of the Bushveld Complex. Reserves are reported
to be exhausted. |
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Iolite (Mg,Fe)2Al4Si5O18 |
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Geological occurrences:
In thermally altered aluminium-rich rocks, gneisses,
schists, granites, pegmatites and alluvial gravels.
The colours of iolite or “water sapphire”,
as known in the trade, may vary from deep blue, violet
blue to greyish blue. Iolite has three pleochroic colours
and is thus trichroic. The colours range from violet
blue to colourless and greyish yellow. Neargem- quality
iolite has been reported in the vicinity of Hout Bay,
Western Cape Province and Namaqualand. Gem-quality iolite
is relatively rare.
Cordilrite (non gem-quality iolite) is present at the
contact of the Bushveld Complex and the shales of the
Transvaal Supergroup owing to contact metamorphism.
Occurrences are reported from Mpumalanga Province, as
well as at areas in the Northwest Province. Lenses of
massive cordierite occur in slates near the contact
of the Cape Granite and rocks of the Cape Supergroup.
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Quartz SiO2 |
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Geological occurrences:
quartz is a constituent of many igneous, metamorphic
and sedimentary rocks. It also occurs in unconsolidated
sand and gravel deposits. Quartz is deposited in rocks
of all ages and is the most common of all minerals.
It is also a very important rock-forming mineral. It
may be divided into crystalline and cryptocrystalline
quartz. |
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Crystalline Quartz: Rock Crystal SiO2: |
Clear. These colourless,
doubly terminated crystals are also known in the trade
as “Herkimer diamond” or “rhinestone”.
They occur mainly in granites and pegmatitic veins.
It is collected as mineral specimens because excellent
crystals are common. At the Messina mines large crystals
up to 0.5 m in length have been recovered. |
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Smoky Quartz SiO2(cairngorm): |
Owes its colourless-to-black
(morion) colour to a possible combination of natural
irradiation, but the crystal is not radioactive. The
large crystals occur in cavities in granite and pegmatite
and can be transparent to opaque. Occurrences include
those at the Potgietersrus tin mines, Groblersdal district,
Barberton district, Namaqualand, Gordonia district and
near Xarroies, Northern Cape Province. |
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Amethyst SiO2: |
The colour varies
from deep purple to light violet and is caused primarily
by iron oxide. Small amounts of titanium and/or manganese
are also present. The colouration is in patches and
zones, and rarely uniform. Amethyst is found in geodes
(cavities), where the terminations of the crystals are
amethyst and the rest often colourless rock crystal.
Crystals are transparent to translucent. Gem-quality
amethyst is deep purple in colour and is usually facetted.
Amethyst is also manufactured synthetically and is cut
and used as gemstones, but its price is not much less
than that of the natural gemstone. Amethyst is found
in the Northern Cape Province, Gordonia district and
Gauteng Province (poorquality crystals). Better-quality
amethyst is found near Pofadder. |
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Citrine SiO2: |
This yellow to golden-brown
quartz type is coloured by iron oxide. It is still occasionally
called “topaz quartz”, but this is a misleading
term that should not be used. The occurrence and habit
of citrine are similar to those of amethyst. Although
citrine is not very valuable as a gemstone, it is being
synthesized on a large scale. Purple amethyst turns
yellow (or green) after heat treatment and therefore
many heat-treated amethysts are marketed as citrine.
Amethyst-citrine quartz (also known as ametrine) shows
amethyst (purple) and citrine (yellow) colours together
in the same crystal. Quartz is one of the most com -
mon minerals, appearing in a vari - ety of beautiful
colours, and in an extraordinary perfect hexagonal crystal
form. In some cases, one or both colours are artificially
induced by heat treatment. Natural ametrine is known,
but does not occur in South Africa. Citrine is found
at Jagersfontein, Free State Province. |
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Rose Quartz SiO2: |
The colour of this
variety ranges from from pale to deep pink (“strawberry”
quartz) due to traces of titanium in its structure.
It occurs massive in pegmatites, but is almost always
included and cracked. Distinct crystals are very rare.
Rutile-needle inclusions give rise to a bluish appearance,
also known as blue quartz. It is used in the trade as
beads, pendants or ornaments. Localities include the
Northern Province, Namaqualand district, Gordonia district,
Kenhardt district, Prieska- Upington area and at Jakkalswater.
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Cryptocrystalline (finely crystalline) Quartz: Chalcedony
SiO2: |
This is the general
term for finegrained, fibrous quartz. Chalcedony often
forms concretionary deposits, usually mamillary, botryoidal
or stalactitic. It also occurs as filling in cavities
in basalts (igneous rock consisting of minerals plagioclase
and augite) and replacements of organic material. The
colour ranges from white, through grey and blue to brown
and it is transparent to translucent. The various coloured
varieties of chalcedony have names such as chrysoprase
(green), sard (brown), heliotrope (dark green) and carnelian
(reddishbrown). Chalcedony is found near Prieska, Northern
Cape Province. |
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Agate SiO2: |
This is distinctly
banded chalcedony with successive layers differing in
colour. Agate forms as a filling in volcanic rocks (Drakensberg
basalts), but is often found concentrated in river gravels.
The centre of the cavity is often filled with crystalline
quartz or chalcedony or may be empty. The bands are
formed by the precipitation of silica, layer by layer,
from the outside of the cavity inwards. Often alluvial
diamond deposits, such as those in the Orange, Vaal
and Caledon Rivers also contain agate. Much of the commercially
produced agate is artificially coloured by chemical
treatments. All varieties are cut into cabochons, beads,
engravings and cameos. |
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Lace Agate SiO2: |
cameos. Lace Agate
SiO2: This translucent chalcedony, with blue and white
bands, occurs near Springbok, in the Northern Cape Province.
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Moss Agate SiO2: |
The grey, bluish or
milky transparent to translucent chalcedony, where chemical
precipitation of iron (red), manganese (black), or chlorite
(green) oxide depicts a organic, moss appearance. Poor-quality
moss agate is found in the vicinity of Lichtenburg and
on the slopes of the Lebombo Mountains, KwaZulu-Natal.
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Onyx SiO2: |
This is banded agate
in a limited range of band colours (black and white
or grey and white). Onyx is also artificially coloured
by chemical treatment.
Occurrences include KwaZulu-Natal Province, Postmasburg,
Barkly West, Hopetown, Lichtenburg and Pilgrim’s
Rest. |
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Rainbow Chalcedony SiO2: |
A varicoloured chalcedony
in which the presence of iron and manganese contributes
to the brilliant colours which include white, yellow,
red, brown, blue, grey and black. Banded black and white
stones are known as zebra stones. Localities are in
the Prieska district. |
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Aventurine SiO2: |
This is an apple-green
chalcedony with spots of chromium-rich muscovite occurring
at Gravelotte and Leydsdorp. |
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Carnelian SiO2: |
An orange to brownish
chalcedony found in volcanic rocks and also in alluvial
diamonds diggings of Kimberley and Lichtenburg. |
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Jasper SiO2: |
This variety is a
massive, fine crystalline quartz coloured by iron oxide.
Jasper has an opaque appearance. The colour is most
often red, but can be
brown, yellow and even green due to chlorite (rare green
jasper). Brecciated jasper is also known as zylite.
Banded red jasper is layered, with layer thickness varying
from a few millimetres to more than 100 mm. Occurrences
are restricted to the Postmasburg, Kuruman and Hay districts,
Northern Cape Province. |
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Opal SiO2 .H2O : |
The chemical composition
of opal is silica, with up to 10 % water. The structure
is non-crystalline and opal consists of very small silica
spheres, visible only through a Scanning Electron Microscope.
The play of colour is caused by these silica spheres
diffracting the light. Opal occurs as a low-temperature
mineral in surface deposits. It is also deposited from
low-temperature silica-bearing water and may occur in
sedimentary, igneous or metamorphic rocks. It may also
act as a replacement mineral, e.g. opalised wood. Common
opal is semi-translucent to opaque, colourless, white
or coloured (impurities). The gem varieties include:
White opal with colour play (iridescence), black opal
with bright colour effect and fire-opal which is transparent
to translucent brownish yellow to orange. Fire opal
may be faceted and other varieties are cut as cabochons,
carvings and beads. Common opal occurs locally in large
quantities in the vicinity of Rustenburg, Gordonia district,
and from the Northwest Province usually in the gossan
(weathered crusts) of basic rocks or as leaching products
of sulphide- rich pipes. No gem opals occur in South
Africa |
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Tiger’s eye SiO2: |
South Africa’s
crocidolite and tiger ’s eye deposits are amongst
the few in the world that are economically important
and mineable. Although the deposits of gem-quality tiger’s
eye are very large, they occur only in the banded- iron
formations of the northern part of the Northern Cape
Province. The crocidolite deposits stretch from Prieska
in the south, to Kuruman in the north, a distance of
400 km, and occur in a range of hills known as the Asbestos
Hills in the south,and the Kuruman Hills in the north.
Crocidolite, or blue asbestos, is a fine, fibrous form
of the soda-amphibole riebeckite [NaFe+2Fe+3Si8O22/(OH)2].
The fibrous nature of the crocidolite is not related
to dynamic metamorphism, but to low-temperature dehydration
and slight ionic rearrangement. In the weathered zone,
crocidolite becomes brown and brittle. Under some circumstances
the fibres can be replaced by silica while retaining
the general outward appearance of the asbestos. This
gives rise to the so-called tiger’s eye quartz
(93%-97% quartz). Tiger’s eye is yellow and brown
in colour. Other variety names include “hawk’s
eye” (grey and green), “zebra” (yellow
and green/blue), “cat’s eye” (blue
- a form of unweathered crocidolite) and “bull’s
eye” (red). The last mentioned does not occur
in nature, but is obtained by heating tiger’s
eye to approximately 400OC Tiger’s eye deposits
are found in the vicinity of Niekerkshoop, Prieska and
Hay districts and Vryburg district, Northern Cape Province.
Reserves have not been quantified, but are large. Mining
is by means of open-cast quarries. Tiger’s eye
is not manufactured synthetically. |
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